英语翻译Compound 5a:Yield 72.1% of oil; 1H NMR (300 MHz,CDCl 3)

英语翻译
Compound 5a:Yield 72.1% of oil; 1H NMR (300 MHz,CDCl 3) 7.70-7.74 (m,2H,3-Ph-2,6-2H),7.46-7.52 (m,3H,Ph-6-H+3-Ph-3,5-2H),7.34-7.37 (m,2H,Ph-3,5-2H),7.27-7.29 (m,1H,3-Ph-4-H),7.24-7.25 (m,1H,Ph-4-H),5.79 (s,1H,Py-4-H),5.02 (s,2H,CH 2),4.06 (s,3H,OCH 3),3.85 (s,3H,CO 2CH 3),3.69 (s,3H,NCH 3); Anal.Calcd for:C,66.48; H,5.58; N,11.08; Found:C,66.19; H,5.67; N,10.99.
Compound 5b:Yield 68.7% of a white solid,m.p.102-105 oC; 1 H NMR (300 MHz,CDCl 3) 7.61-7.66 (m,2H,3-Ph-2,6-2H),7.55-7.57 (m,1H,Ph-6-H),7.38-7.43 (m,2H,3-Ph-3,5-2H),7.30-7.33 (m,2H,Ph-3,5-2H),7.23-7.25 (m,1H,Ph-4-H),5.75 (s,1H,Py-4-H),5.02 (s,2H,CH 2),4.05 (s,3H,OCH 3),3.85 (s,3H,CO 2CH3),3.68 (s,3H,NCH 3); Anal.Calcd for:C,60.95; H,4.87; N,10.15; Found:C,61.04; H,4.76; N,10.12.
Compound 5c:Yield 75.0% of a white solid,m.p.86-88 oC; 1H NMR (300 MHz,CDCl 3) 7.60-7.63 (d,J=7.5H Z,1H,Ph-6-H),7.40-7.46 (m,4H,Ph-3,5-2H+ 3-Ph-2,6-2H),7.18-7.23 (m,3H,3-Ph-3,5-2H+Ph-4-H),5.65 (s,1H,Py-4-H),5.15 (s,2H,CH 2),4.04 (s,3H,NOCH 3),3.86 (s,3H,CO 2CH 3),3.73 (s,3H,NCH 3),1.37 (s,9H,t-Bu); Anal.Calcd for:C,68.95; H,6.71; N,9.65; Found:C,68.78; H,6.77; N,9.60.
Compound 5d:Yield 69.4% of a white solid,m.p.117-118 oC; IR(KBr)_:2930 (s,C-H),1730 (s,C=O),1550 (w,aromatic rings),1520 (s,C=N),1450 (s,CH 3),1220 (m,C-N),770,750 (s,Ph-H)cm -1; 1H NMR (300 MHz,CDCl 3) _7.52-7.57 (m,2H,Ph-6-H+3-Ph-2-H),7.42-7.46 (m,3H,Ph-3,5-2H+3-Ph-6-H),7.22-7.25 (m,1H,Ph-4-H),7.11-7.14 (d,J=8.1H Z,1H,3-Ph-5-H),5.75 (s,1H,Py-4-H),5.00 (s,2H,CH 2),4.05 (s,3H,NOCH 3),3.84 (s,3H,CO 2CH 3),3.67 (s,3H,NCH 3),2.28 (s,3H,3-CH 3),2.26 (s,3H,4-CH 3).
Compound 5e:Yield 70.3% of oil; 1 H NMR (300 MHz,CDCl 3) 7.60-7.63 (d,1H,J=7.2H Z,Ph-6-H),7.40-7.44 (m,2H,Ph-3,5-2H),7.19 (m,1H,Ph-4-H),7.03-7.10 (m,3H,3-Ph-3,5,6-3H),5.55 (s,1H,Py-4-H),5.08 (s,2H,CH 2),4.04 (s,3H,NOCH 3),3.84 (s,3H,CO 2CH 3),3.48 (s,3H,CH 3),2.36 (s,3H,2-CH 3),2.15 (s,3H,4-CH 3); Found:C,67.66; H,6.12; N,10.28.Anal.Calcd for:C,67.80; H,6.18; N,10.31;

化合物的产量72.1% 5a:油,核磁共振氢谱(300兆赫,CDCl 3)吗?7.70-7.74 2H,3-Ph-2(m,6-2H),7.46-7.52,Ph-6-H(m + 3-Ph-3 3H,5-2H),7.34-7.37 2H,Ph-3(m,5-2H),7.27-7.29,(m、质,3-Ph-4-H),7.24-7.25(m、质,Ph-4-H 5.79(s)、质,Py-4-H),五月二日(s,双手,2),全球年平均销售额突破40.6(CH s、3H,OCH 3),385(s,3H,CO针率(3)、(s,3H,3);NCH肛门.Calcd 66.48为:C、H、5.58;;氮、11.08;发现:C,66.19;H、56.7;氮、10.99.
化合物的产量68.7% 5b:本品为白色固体.102-105,m.p(oC);1磁共振(300兆赫,CDCl 3)吗?7.61-7.66 2H,3-Ph-2(m,6-2H),7.55-7.57,(m、质,Ph-6-H),7.38-7.43 2H,3-Ph-3(m,5-2H),7.30-7.33,Ph-3 2H(m),7.23-7.25,5-2H(m、质,Ph-4-H 57.5(s)、质,Py-4-H),五月二日(s,双手,CH二),(s,4.05 3H,OCH 3),385(s,3H,CO 2CH3),达到368(NCH 3H,s,3);肛门.Calcd 60.95为:C、H、4.87;;氮、10.15,发现:C,61.04;H、476;氮、创汇1012.
复合5c:产量以学业需求的.86-88白色固体,m.p核磁共振氢谱(oC);(3)300兆赫,CDCl吗?7.60-7.63(d、J = 7.5H Z、质,Ph-6-H),7.40-7.46 4H,Ph-3(m,5-2H + 3-Ph-2,6-2H,(m),7.18-7.23 3H,3-Ph-3,5-2H,Ph-4-H),5.65 +(s、质,Py-4-H 5.15(s),2),双手,CH,达(s,3H,还有3),3.86(s,3H,CO针(3),3.73 NCH s、3H,3),1.37(s,9H,t-Bu);肛门.Calcd为:C,68.95;H、6.71;氮、9.65;发现:C、H、6.77 68.78;;氮、9.60.
复合5d:产量的白色固体,儿占69.4%(oC 117-118 m.p;红外光谱(.)_:KBr C-H 2930(s,s)、1730(C = O),(w、芳香环1550年),1520(s、C = N),1450(s,CH 3)、1220(m,C-N),770、750(s,Ph-H)厘米;核磁共振氢谱对产物- 1(300兆赫,CDCl _7.52-7.57(3),Ph-6-H米,3-Ph-2-H 2H),7.42-7.46 + 3H,Ph-3(m,5-2H + 3-Ph-6-H,(m),7.22-7.25、质,Ph-4-H),7.11-7.14(d、J = 8.1H Z、质,3-Ph-5-H 57.5(s)、质,Py-4-H(s)、5.00,双手,CH 2),4.05(s,3H,还有3),3.84(s,3H,CO针(3),3.67所示,s,3H NCH 3),2.28(s,3H,3-CH 2.26(3),4-CH s、3H,3).
杀灭率可达70.3%的复合5e:产量;1核磁氢谱对油(300兆赫,CDCl 3)7.60-7.63(d、质,J = 7.2H Z,Ph-6-H),7.40-7.44 2H,Ph-3(m,5-2H),7.19中的,(m、质,Ph-4-H),7.03-7.10 3H,3-Ph-3(m,、5、6-3H 55.5(s)、质,Py-4-H 508(s),2),双手,CH,达(s,3H,还有3),3.84 3H,CO(s,(3)、3.48分锁,CH 3H s,3),急需的(s,3H,3),2.15里(s,4-CH 3H,3);发现:C,67.66;H、6.12;氮、10.28.肛门.Calcd为:C,67.80;H,6.18;氮、10.31;