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During the Olympic Games many people served as volunteers,(

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During the Olympic Games many people served as volunteers,( ) were young college students .
A most of them B most of which C most of whom D most of what
但是我想问一下,这个先行词在从句中不是做主语吗?而WHOM是引导宾语的,为什么选C?如果选项有 most of who ,这个选项对吗?
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1. 答案的确是C.
2. 先行词whom在定语从句中并不做主语,做主语的是most of whom,即most of the volunteers.
而whom在定语从句中充当介词of的宾语,所以用宾格whom.
3. 所以正确答案是用most of whom,而most of who是错误的.